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ethanol hazards and precautions

Note that for readability purposes, only the pictograms, signal words and hazard statements referred in more than 5% of the notifications under CLP are displayed. This substance can be found in products with material based on: paper (e.g. Ensuring there are no naked flames nearby. It applies the European Agreements on the international transport of dangerous goods by road (ADR) and inland waterways (ADN), and the Regulations concerning the international carriage of dangerous goods by rail (RID). Despite being common and having myriad uses, ethanol is a hazardous chemical and should be treated with care. Éthanol 96%, Ph.Eur., extra pur numéro d'article: P075 Version: 5.0 fr Remplace la version de: 27.01.2020 Version: (4) date d’établissement: 27.07.2015 Révision: 16.06.2020 France (fr) Page 1 / 17. The vapour can catch fire at 13 °C and is easily ignited by heat or sparks. If it is drunk in its pure form, it can be lethal or cause coma. Advice for firefighters Protective actions during firefighting Cool containers exposed to flames with water until well after the fire is out. CDC - NIOSH Pocket Guide to Chemical Hazards - Ethyl alcohol Skip directly to site content Skip directly to page options Skip directly to A-Z link … Health Hazards Due to Alcohol Abuse Long-term alcohol misuse is associated with liver and cardiovascular disease, cancer, and nervous system damage as well as psychiatric problems such as depression, anxiety, and antisocial personality disorder. Harmonised classification and labelling is a legally binding classification and labelling for a substance, agreed at European Community level. Prendre connaissance de l’étiquetage et de la fiche de données de sécurité du produit (notamment sur les précautions d’emploi et de stockage). ReAgent is one of the leading chemical suppliers in the UK. A prioritisation hierarchy means that data is taken from harmonised C&L data and regulatory lists first, then REACH registrations and finally from CLP notifications. Release to the environment of this substance can occur from industrial use: formulation of mixtures and in processing aids at industrial sites. Food Contact Regenerated Cellulose Directive - Authorised Substances, Workplace Signs - minimum requirements & signs on containers and pipes, Waste Framework Directive, Annex III - Waste - Hazardous Properties, Fertiliser Regulation- Annex I, E.3 (chelating and complexing agents), Substances of very high concern identification, Recommendation for the Authorisation List, Getting started with EU chemicals legislation, Classification of substances and mixtures, Harmonised classification and labelling (CLH). The described Product category (i.e. What is the Classification and Labelling Inventory? cooling liquids in refrigerators, oil-based electric heaters). May form explosive mixture with air at very high concentration. Your distillation area should be well lit, clean and well ventilated to prevent the accumulation of alcoholic vapours. Always wear safety goggles. If the substance is covered by more than one CLH entry (e.g. Other release to the environment of this substance is likely to occur from: indoor use (e.g. This substance is used in the following products: coating products, laboratory chemicals, fuels, washing & cleaning products, anti-freeze products, heat transfer fluids, inks and toners, textile treatment products and dyes, biocides (e.g. Substances indicated, in 2009, as being intended to be registered by at least one company in the EEA. 3 Effective date : 11.19.2014 Page 4 of 9 Ethanol, Lab Grade, 500mL Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Special hazards arising from the substance or mixture: Chemical Hazard : Ethanol is a flammable liquid whose vapours can form ignitable and explosive mixtures with air at normal room temperatures. 2. The CLP Regulation makes sure that the hazards presented by chemicals are clearly communicated to workers and consumers in the European Union. EU. When information is available in all sources, the first two are displayed as a priority. In fact, toxicologists and epidemiologists have acquired good knowledge of the effects and mechanisms of ethanol ingestion. Current commercial production of ethanol is based almost exclusively on starch- and sugar-based feedstocks. Labelling acc. This database contains substances that have been assigned hazard property (HP) waste codes 1-15, as defined in terms of the hazard class & category, hazard (H) statement, and/or concentration limits provided in Annex III of the Waste Framework Directive (2008/98/EC). If generated, an InChI string will also be generated and made available for searching. Bondloc Hand Sanitiser (Ethanol) Specific hazards Highly flammable liquid and vapour. Ethanol is a strongly-smelling, volatile, flammable liquid – so yes, the short answer is that ethanol is hazardous! Material Safety Data Sheet, Misc. No smoking. Ethanol is a corrosive chemical and on an industrial level should be kept in stainless steel containers. Other relevant information includes the following: To see the full list of notified classifications and to get more information on impurities and additives relevant to classification please consult the C&L Inventory. Dangerous Goods List (RID, Chap. Some data submitters indicate they consider this substance as Carcinogenic. When mixed … Thus, an aqueous mixture containing 30% ethanol can produce a flammable mixture of vapour and air at 29⁰C, and even one containing only 5% alcohol can produce a flammable mixture at 62⁰C.1 Ethanol is a flammable liquid. At ReAgent, we sell ethanol in sizes ranging from 500ml to 2.5 litres. Label elements Signal word Warning Hazard statement Flammable liquid and vapor. The use information is displayed per substance life cycle stage (consumer use, in articles, by professional workers (widespread uses), in formulation or re-packing, at industrial sites or in manufacturing). Direct ingestion of more than 10mL can cause permanent blindness by destruction of the optic nerve, poisoning of the central nervous system, coma and possibly death. Danger! Here you can find all of the regulations and regulatory lists in which this substance appears, according to the data available to ECHA. This list contains the substances and substance groups authorized by the EU in the manufacture of regenerated cellulose film intended to come into contact with foodstuffs. Non-Exhaustive List of Banned Substances, Directive 94/33/EC on Young People at Work, 20 August 1994, as amended by Dir 2014/27/EU, March 5, 2014 (Based on Table 3 of Annex VI to CLP, inter alia), EU. Even though ethanol is very commonly used, it is a dangerous chemical. – flush your eyes for at least 15 minutes and contact the emergency services. Electrocution hazard. manufacturers. Allow sufficient space to work in. Information on applicable regulatory frameworks is also automatically generated and may not be complete or up to date. Hazardous … Compendium of Chemical Hazards: Ethanol Page 5 of 15 Incident Management Physicochemical Properties CAS number 64-17-5 Molecular weight 46.07 Formula C 2 H 6 O Common synonyms Ethyl alcohol, grain alcohol State at room temperature Clear, colourless liquid Volatility 59.3 mmHg at 25°C, volatile Specific gravity 0.8 (water = 1) Flammability Highly flammable In that case, the ATP (Adaptation to Technical Progress) number is displayed. This section provides an overview of the calculated volume at which the substance is manufactured or imported to the European Economic Area (EU28 + Iceland, Liechtenstein and Norway). If there is a substantial ethanol spill, make Food Contact Regenerated Cellulose Directive - Authorised Substances, EU Ecolabels - Restrictions for Hazardous Substances/Mixtures, FCM and Articles Regulation, Annex I - Authorised Substances, ETHANOL (ETHYL ALCOHOL) or ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION), Inland Transport of Dangerous Goods Directive, Annex III - ADN, Inland Transport of Dangerous Goods Directive, Annex I - ADR, Inland Transport of Dangerous Goods Directive, Annex II - RID, ETHANOL SOLUTION (ETHYL ALCOHOL SOLUTION), CAD - Chemical Agents Directive, Art. It characterizes the product with regard to the appropriate safety precautions. Ethanol is highly inflammable and combustible so keep away from open flame, sparks and ignition sources. The EC or list number is the primary substance identifier used by ECHA. Workplace Signage: Annexes I and III, Directive 92/58/EEC, last amended by Directive 2014/27/EU, 5 March 2014, EU. When heated until it burns, ethanol gives off acrid smoke and fumes. Ethanol was first discovered as a by-product of fermenting alcohol, has been used in chemistry since the 1850s, and due to its versatility is now widely used in industry and homes around the world. A lot of people have raised concerns about potential safety hazards posed by methanol itself and the process of refining it from natural gas. This substance is used in the following products: coating products, fuels, washing & cleaning products, inks and toners, anti-freeze products, adhesives and sealants, non-metal-surface treatment products, heat transfer fluids, polishes and waxes, extraction agents, textile treatment products and dyes, fillers, putties, plasters, modelling clay, metal surface treatment products, leather treatment products and photo-chemicals. Inhalation: High vapor concentrations may cause a burning sensation in the throat and nose, stinging and watering in the eyes. These notifications can be provided by manufacturers, importers and downstream users. This website uses cookies to ensure you get the best experience on our websites. 3.2, Table A), Directive 2008/68/EC, last amended by Regulation 2019/1243/EU, 25 July 2019, EU. A student wants to use a Bunsen burner to heat a test tube of ethanol. This database contains: (1) the list of hazardous substances harmonized for classification and labeling in EU (i.e. This is unique source of information on the chemicals manufactured and imported in Europe. If no EU harmonised classification and labelling exists and the substance was not registered under REACH, information derived from classification and labelling (C&L) notifications to ECHA under CLP Regulation is displayed under this section. Protective clothing should be worn, such as: At home, it’s equally important to make sure that you and anyone else aren’t exposed to ethanol. Additionally, if available, information on the use of the substance and how consumers and workers are likely to be exposed to it can also be displayed here. Union List of Authorized Substances: Annex I, Plastics Food Contact Regulation 10/2011/EU, as amended by Regulation 2020/1245/EU, 3 September 2020, EU. Despite being common and having myriad uses, ethanol is a hazardous chemical and should be treated with care. Despite being common and having myriad uses. The purpose of the information provided under this section is to highlight the substance hazardousness in a readable format. Manipuler en vase clos et à défaut sous hotte aspirante pour éviter l’inhalation de vapeurs. in case of consumer and professional uses). 5.3. disinfectants, pest control products), finger paints, adhesives and sealants, leather treatment products, polishes and waxes, plant protection products, fillers, putties, plasters, modelling clay and lubricants and greases. Unusual Fire and Explosion Hazards: N/A 06. 2. The CAS number is the substance numerical identifier assigned by the Chemical Abstracts Service, a division of the American Chemical Society, to substances registered in the CAS registry database. There are a number of reasons why ethanol is hazardous: Ethanol Is Flammable. Accidental release measures Personal precautions, protective equipment and emergency procedures: Wear protective equipment. 7 and points 2 and 3 of the Annex to Directive 94/33/EC, to which young persons (under 18 years of age) may not be exposed at the workplace. IMDG UN3475 Ethanol and gasoline mixture 3 PG II No IATA UN3475 Ethanol and gasoline mixture 3 PG II No Transport in bulk (according to Annex II of MARPOL 73/78 and the IBC Code): Not applicable. More information about Classification and Labelling is available in the Regulations section of ECHA website. This information has not been reviewed or verified by ECHA, and may change without prior notice. Information on precautionary measures and the safe use is submitted by the registrant of a substance and the registrant is solely responsible for its accuracy and completeness. The ‘Hazard classification’ and labelling section uses the signal word, pictogram(s) and hazard statements of the substance under the harmonised classification and labelling (CLH) as its primary source of information. Proposals for new, or updates to existing harmonised classification and labelling of substances. When in a concentration of more than 50%, ethanol causes local mucosal lesions through dehydration and albumin precipitation. Dry chemical extinguisher, foam and water are effective in controlling fire. A substance identified primarily by an EC or list number may be linked with more than one CAS number, or with CAS numbers that have been deleted. The molecular structure is based on structures generated from information available in ECHA’s databases. Do not drink anything. 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